Which were the first known fragrance?
The study of fragrance, developed in the Nile Valley, was to inspire other ancient cultures. In Greece, athletes anointed their bodies with aromatic oils, and at banquets Romans refreshed themselves between courses with flower-scented water. It was the Persians who developed the use of exotic ingredients and the technique of extracting oils from flowers through distillation. This expertise was brought to Western Europe at the time of the Crusades.
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Source : fragrancesoftheworld.com